电压对微弧氧化膜抑制7050铝合金氢脆敏感性的影响

为进一步探究微弧氧化膜和7050铝合金的氢脆敏感性之间的关系,采用了湿空气中的慢应变速率拉伸、拉伸断口形貌分析、微弧氧化试样表面形貌分析及氢含量测试等表征手段,验证了微弧氧化膜抑制7050铝合金在湿空气中发生氢脆的机制。结果表明,不同微弧氧化电压下制备的膜层对7050铝合金具有不同的抑制氢脆效果,抑制机制主要由膜阻氢进入试样和膜致附加压应力两个方面组成。     

随钻测量用MIMU信号处理

为提高随钻测量系统的姿态估计精度,克服传统算法对于非平稳信号处理的局限性,提出基于ARIMA模型的卡尔曼滤波算法。该算法采用时间序列分析方法,建立了随机漂移误差的ARIMA模型,根据实测数据的ACF和PACF,确定微机械陀螺仪模型的各个参数,利用卡尔曼滤波算法进行滤波处理。实验对模型的拟合残差均值与方差作了比较分析,通过卡尔曼滤波处理,ARIMA模型数据零偏减小了1个数量级,滤波方差相比传统AR模型减小了42%。所建立的ARIMA模型与传统时间序列方法建模相比,降低了模型预测误差,滤除MEMS陀螺仪随机漂移误差更为明显,模型对提高陀螺仪输出精度更为有效。     

Modeling and Analytical Solution of Hybrid Thermopiezoelectric Micro Actuator and Performance Study Under Changing of Different Parameters

Micro actuators are an irreplaceable part of motion control in miniaturized systems and are intended to have a high range of deformation, high accuracy, large force, and quick response. In this article, an analytical model for a hybrid thermopiezoelectric micro actuator is developed in which a double lead-zirconnate-titanate piezoceramic (PZT) beam structure consisting of two arms with different lengths are used. Governing differential equation of motion and electrical field are derived and solved. Out of parametric studies it was observed that, under application of temperature and voltage gradients, the deflection of the actuator shows different trends depending on the geometry of the micro actuator and also type of PZT material.     

Confined Transformation of UiO‐66 Nanocrystals to Yttria‐Stabilized Zirconia with Hierarchical Pore Structures for Catalytic Applications

Solid acids as a substitution for hazardous liquid acids (e.g., HF and H₂SO₄) can promote many important reactions in the industry, such as carbon cracking, to proceed in a more sustainable way. Starting from a zirconium‐based metal‐organic framework (UiO‐66 nanocrystals), herein a transformative method is reported to prepare micro/mesoporous yttria‐stabilized zirconia (YSZ) encapsulated inside a mesoporous silica shell. It is then further demonstrated that the resultant reactor‐like catalysts can be used for a wide range of catalytic reactions. The acidity of the YSZ phase is found with rich accessible Lewis acid and Brønsted acid sites and they display superior performances for esterification (acetic acid and ethanol) and Friedel‐Crafts alkylation (benzylation of toluene). After being loaded with different noble metals, furthermore, hydrogenation of CO₂ and a one‐pot cascade reaction (nitrobenzene and benzaldehyde to N‐benzylaniline) are used as model reactions to prove the versatility and stability of catalysts. Based on the findings of this work, it is believed that this class of reactor‐like catalysts can meet future challenges in the development of new catalyst technology for greener heterogeneous catalysis.     

多元合金化大断面球墨铸铁组织和性能的分析

为了提升大断面球墨铸铁综合力学性能，通过复合添加微量合金元素铜、锑、锡、钼对大断面球墨铸铁进行微合金化处理，借助金相显微镜(OM)、扫描电子显微镜(SEM)及力学性能测试等手段，研究了Cu Sb Sn Mo复合微合金化大断面球墨铸铁微观组织和力学性能。结果表明，试验球墨铸铁具有良好的综合力学性能。大断面球墨铸铁中添加铜、锑、锡、钼后优化了材料的组织结构，基体组织为珠光体＋少量牛眼状铁素体；试样石墨组织细小、圆整，分布均匀。同时，合金元素的复合加入使得其抗拉强度达到800 MPa以上，硬度约为280HB，伸长率达到5%以上。拉伸断口分析表明，微合金化大断面球墨铸铁断裂模式以解理断裂为主，伴有少量的塑性变形。     

Ti6Al4V钛合金表面蓝色微弧氧化膜的制备及性能

利用微弧氧化技术在Ti6Al4V钛合金表面制备出蓝色微弧氧化膜。对微弧氧化膜的微观形貌和元素组成进行了分析,并对微弧氧化膜的显微硬度进行了测试。结果表明:微弧氧化膜表面光整,呈均匀深蓝色,其主要由Ti、Mn、O和C四种元素组成,还含有少量的V、Al和Si元素;微弧氧化膜的表面粗糙度约为0.159μm,与钛合金的表面粗糙度相近;微弧氧化膜的显微硬度为5 437.4 MPa,显著高于钛合金的显微硬度。     

基于灰色关联度的微孔端面机械密封开启力共性影响参数分析

目前微孔端面机械密封采用的几何参数繁多,缺乏明确物理意义。为找出跨孔型的共性几何参数,基于Fluent多相流空化模型,针对矩形孔、菱形孔、椭圆孔端面机械密封,建立密封间隙流体的三维数值计算模型,计算得到144条开启力数据;在分析开启力和几何尺寸之间的关系、额外开启力产生机制的基础上,提出等效长度和等效宽度2个具有物理意义的几何参数;采用灰色关联度分析法,分析和验证等效长度、等效宽度、方向角、面积比对开启力的影响,发现4个因素对3种微孔密封的间隙流体开启力都有影响,但等效长度与等效宽度的影响较方向角、面积比大。